Publication
Title
Transition metal-free synthesis of carbamates using CO₂ as the carbon source
Author
Abstract
Utilization of carbon dioxide as a C1 synthon is highly attractive for the synthesis of valuable chemicals. However, activation of CO2 is highly challenging, owing to its thermodynamic stability and kinetic inertness. With this in mind, several strategies have been developed for the generation of carbon-heteroatom bonds. Among these, formation of C-N bonds is highly attractive, especially, when carbamates can be synthesized directly from CO2. This Minireview focuses on transition metal-free approaches for the fixation of CO2 to generate carbamates for the production of fine chemicals and pharmaceuticals. Within the past decade, transition metal-free approaches have gained increasing attention, but traditional reviews have rarely focused on these approaches. Direct comparisons between such methods have been even more scarce. This Minireview seeks to address this discrepancy.
Language
English
Source (journal)
Chemsuschem. - Weinheim
Publication
Weinheim : Wiley-v c h verlag gmbh , 2020
ISSN
1864-5631
DOI
10.1002/CSSC.202002073
Volume/pages
13 :23 (2020) , p. 6246-6258
ISI
000583883500001
Pubmed ID
33107690
Full text (Publisher's DOI)
Full text (open access)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 01.12.2020
Last edited 12.12.2024
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