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Title
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Reactive plasma cleaning and restoration of transition metal dichalcogenide monolayers
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Author
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Abstract
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| The cleaning of two-dimensional (2D) materials is an essential step in the fabrication of future devices, leveraging their unique physical, optical, and chemical properties. Part of these emerging 2D materials are transition metal dichalcogenides (TMDs). So far there is limited understanding of the cleaning of “monolayer” TMD materials. In this study, we report on the use of downstream H 2 plasma to clean the surface of monolayer WS 2 grown by MOCVD. We demonstrate that high-temperature processing is essential, allowing to maximize the removal rate of polymers and to mitigate damage caused to the WS 2 in the form of sulfur vacancies. We show that low temperature in situ carbonyl sulfide (OCS) soak is an efficient way to resulfurize the material, besides high-temperature H 2 S annealing. The cleaning processes and mechanisms elucidated in this work are tested on back-gated field-effect transistors, confirming that transport properties of WS 2 devices can be maintained by the combination of H 2 plasma cleaning and OCS restoration. The low-damage plasma cleaning based on H 2 and OCS is very reproducible, fast (completed in a few minutes) and uses a 300 mm industrial plasma etch system qualified for standard semiconductor pilot production. This process is, therefore, expected to enable the industrial scale-up of 2D-based devices, co-integrated with silicon technology. |
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Language
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English
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Source (journal)
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npj 2D Materials and Applications / Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa (FCT NOVA)-European Materials Research Society (E-MRS)
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Publication
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Nature Publishing Group
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2021
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ISSN
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2397-7132
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DOI
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10.1038/S41699-020-00197-7
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Volume/pages
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5
:1
(2021)
, 10 p.
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Article Reference
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17
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ISI
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000613258900001
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Medium
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E-only publicatie
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Full text (Publisher's DOI)
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Full text (open access)
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