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Title
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Strategic design and synthesis of star-shaped organic linkers for mesoporous MOFs
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Author
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Abstract
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| In the process of designing new MOFs with the aim of having a specific morphology, the shape of the linkers and the choice of coordinating metals have major importance. In this study, the aim to create novel hnb non-interpenetrating MOFs led us to choose tritopic linkers. Novel star-shaped molecules, presenting trigonal geometry and based on aromatic rings, were synthesized. For more convenient synthesis of the library, C-C coupling reactions via a direct arylation methodology were performed. This new synthetic tool, together with the idea of a molecule as a modular combination of smaller building blocks, made possible the fast, cheap and reproducible production of this class of compounds and also its scale-up. With one of the compounds, a MOF was synthesized and characterised via its specific surface area, which varies between 1681 and 3770 m(2) g(-1). |
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Language
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English
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Source (journal)
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Faraday discussions / Royal Society of Chemistry. Faraday Division [Londen] - London
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Publication
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Cambridge
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Royal soc chemistry
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2021
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ISSN
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1359-6640
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DOI
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10.1039/D1FD00026H
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Volume/pages
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231
(2021)
, p. 97-111
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ISI
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000668607500001
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Pubmed ID
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34196337
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Full text (Publisher's DOI)
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