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Title
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1,3,7-triazapyrene-based ortho-carborane fluorophores : convenient synthesis, theoretical studies, and aggregation-induced emission properties
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Author
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Abstract
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| A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C–H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects. |
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Language
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English
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Source (journal)
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Organometallics / American Chemical Society. - Columbus, Ohio
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Publication
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Columbus, Ohio
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2021
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ISSN
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0276-7333
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DOI
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10.1021/ACS.ORGANOMET.1C00234
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Volume/pages
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40
:16
(2021)
, p. 2792-2807
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ISI
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000688246500004
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Full text (Publisher's DOI)
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Full text (open access)
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Full text (publisher's version - intranet only)
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