Publication
Title
Stabilization of the perovskite phase in the Y-Bi-O system by using a BaBiO₃ buffer layer
Author
Abstract
A topological insulating phase has theoretically been predicted for the thermodynamically unstable perovskite phase of YBiO3. Here, it is shown that the crystal structure of the Y-Bi-O system can be controlled by using a BaBiO3 buffer layer. The BaBiO3 film overcomes the large lattice mismatch of 12% with the SrTiO3 substrate by forming a rocksalt structure in between the two perovskite structures. Depositing an YBiO3 film directly on a SrTiO3 substrate gives a fluorite structure. However, when the Y-Bi-O system is deposited on top of the buffer layer with the correct crystal phase and comparable lattice constant, a single oriented perovskite structure with the expected lattice constants is observed.
Language
English
Source (journal)
Physica status solidi: rapid research letters. - Berlin
Publication
Berlin : 2019
ISSN
1862-6254
DOI
10.1002/PSSR.201800679
Volume/pages
13 :7 (2019) , 8 p.
Article Reference
1800679
ISI
000477671800005
Medium
E-only publicatie
Full text (Publisher's DOI)
Full text (open access)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Project info
SOLARPAINT: Understanding the durability of light sensitive materials: transferring insights between solar cell physics and the chemistry of paintings.
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 28.09.2021
Last edited 18.12.2024
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