Title
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Stabilization of the perovskite phase in the Y-Bi-O system by using a BaBiO₃ buffer layer
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Author
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Abstract
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A topological insulating phase has theoretically been predicted for the thermodynamically unstable perovskite phase of YBiO3. Here, it is shown that the crystal structure of the Y-Bi-O system can be controlled by using a BaBiO3 buffer layer. The BaBiO3 film overcomes the large lattice mismatch of 12% with the SrTiO3 substrate by forming a rocksalt structure in between the two perovskite structures. Depositing an YBiO3 film directly on a SrTiO3 substrate gives a fluorite structure. However, when the Y-Bi-O system is deposited on top of the buffer layer with the correct crystal phase and comparable lattice constant, a single oriented perovskite structure with the expected lattice constants is observed. |
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Language
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English
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Source (journal)
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Physica status solidi: rapid research letters. - Berlin
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Publication
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Berlin
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2019
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ISSN
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1862-6254
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DOI
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10.1002/PSSR.201800679
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Volume/pages
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13
:7
(2019)
, 8 p.
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Article Reference
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1800679
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ISI
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000477671800005
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Medium
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E-only publicatie
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Full text (Publisher's DOI)
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Full text (open access)
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Full text (publisher's version - intranet only)
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