Publication
Title
Photo-responsive metal-organic frameworks - design strategies and emerging applications in photocatalysis and adsorption
Author
Abstract
Stimuli-responsive metal-organic frameworks (MOFs) are highly versatile porous materials with the ability to respond to different external stimuli, including temperature, pressure, pH, and light. The MOF properties can switch reversibly under specific light irradiation, opening the doors to various applications. This review focuses on design strategies to obtain photo-responsive MOFs, namely (i) encapsulation of photo-switchable molecules as guests in MOF porous structures, (ii) fabrication of MOF composites, (iii) post-synthesis modification, and (iv) synthesis of MOFs with photo-responsive ligands. The most recent reports from the literature are herein reviewed and analyzed in terms of material chemistry and performance. Comparisons between the different strategies are performed and future challenges are discussed. The critical aspect of the fatigue of photo-responsive MOFs applied for prolonged cycling of irradiation is also discussed.
Language
English
Source (journal)
MATERIALS ADVANCES
Publication
Cambridge : Royal soc chemistry , 2023
DOI
10.1039/D2MA01022D
Volume/pages
4 :5 (2023) , p. 1258-1285
ISI
000938241000001
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Research group
Publication type
Subject
External links
Web of Science
Record
Identifier
Creation 04.10.2023
Last edited 05.10.2023
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