Publication
Title
Hydrogen and Propane Production From Butyric Acid Photoreforming Over Pt-TiO2
Author
Abstract
Photocatalysis is a promising technology from economic, energetic, and ecological points of view because it takes advantage of solar light. Hence, it is one of the investigated green routes to produce hydrogen from renewable energy resources. Butyric acid (BA) is largely present in wastewater and as an intermediate product in anaerobic digestion and therefore it is an inexpensive resource, which can be converted to valuable chemicals. In this work, photoreforming of butyric acid (BAPR) under UV light in aqueous suspensions of platinum-modified titanium dioxide-based catalysts is reported for the first time. Titania nanotubes (TNT) synthesized and calcined at different temperatures (300, 400, 500 degrees C) and commercial TiO2 (P25), decorated with platinum nanoparticles, have been tested and characterized through different techniques including X-ray powder diffraction, UV-vis diffuse reflectance and photoluminescence spectroscopy, transmission electron microscopy, BET and porosimetry analysis. The main identified products of the BAPR were H-2, propane, CO2 and several organic acids (e.g., pentanoic and 3-methylhexanoic acid). It has been found that the morphology and crystallinity of the photocatalysts affected dramatically their optical properties and, consequently, the reaction rate and the product distribution. Specifically, the highest conversion of BA (X-BA) and selectivity toward H-2 (S-H2) was recorded with P25-Pt (X-BA = 26.9%, S-H2 = 47.2% after 8 h of irradiation). TNT-400-Pt showed the highest selectivity toward propane (S-C3H8 = 16.1%) with X-BA = 23.4% and S-H2 = 36.2%. The activity results in conjunction with the characterization of the catalysts highlighted that the main factor affecting the activity in terms of X-BA and generation of H-2 was the crystallinity, and in particular the presence of rutile phase in TiO2, whereas S-C3H8 appears to increase when the electron-holes recombination is lower.
Language
English
Source (journal)
Frontiers in Chemistry
Publication
2019
ISSN
2296-2646
DOI
10.3389/FCHEM.2019.00563
Volume/pages
7 (2019) , 14 p.
Article Reference
563
ISI
000479124800001
Pubmed ID
31440501
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Publication type
Subject
External links
Web of Science
Record
Identifier
Creation 04.10.2023
Last edited 05.10.2023
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