Publication
Title
Identification of volatile organic compounds and their sources driving ozone and secondary organic aerosol formation in NE Spain
Author
Abstract
Volatile organic compounds (VOCs) play a crucial role in the formation of ozone (O3) and secondary organic aerosol (SOA). We conducted measurements of VOC ambient mixing ratios during both summer and winter at two stations: a Barcelona urban background station (BCN) and the Montseny rural background station (MSY). Subsequently, we employed positive matrix factorization (PMF) to analyze the VOC mixing ratios and identify their sources. Our analysis revealed five common sources: anthropogenic I (traffic & industries); anthropogenic II (traffic & biomass burning); isoprene oxidation; monoterpenes; long-lifetime VOCs. To assess the impact of these VOCs on the formation of secondary pollutants, we calculated the ozone formation potential (OFP) and secondary organic aerosol formation potential (SOAP) associated with each VOC. In conclusion, our study provides insights into the sources of VOCs and their contributions to the formation of ozone and SOA in NE Spain. The OFP was primarily influenced by anthropogenic aromatic compounds from the traffic & industries source at BCN (38-49 %) and during winter at MSY (34 %). In contrast, the summer OFP at MSY was primarily driven by biogenic contributions from monoterpenes and isoprene oxidation products (45 %). Acetaldehyde (10-35 %) and methanol (13-14 %) also made significant OFP contributions at both stations. Anthropogenic aromatic com-pounds originating from traffic, industries, and biomass burning played a dominant role (88-93 %) in SOA formation at both stations during both seasons. The only exception was during the summer at MSY, where monoterpenes became the primary driver of SOA formation (41 %). These findings emphasize the importance of considering both anthropogenic and biogenic VOCs in air quality management strategies.
Language
English
Source (journal)
The science of the total environment. - Amsterdam, 1972, currens
Publication
Amsterdam : 2024
ISSN
0048-9697 [print]
1879-1026 [online]
DOI
10.1016/J.SCITOTENV.2023.167159
Volume/pages
906 (2024) , p. 1-20
Article Reference
167159
ISI
001089223300001
Pubmed ID
37758152
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 04.12.2023
Last edited 06.12.2023
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