Publication
Title
Correlated x-ray fluorescence and ptychographic nano-tomography on Rembrandt's The Night Watch reveals unknown lead "layer"
Author
Abstract
The Night Watch, one of the most famous masterpieces by Rembrandt, is the subject of a large research and conservation project. For the conservation treatment, it is of great importance to understand its current condition. Correlated nano-tomography using x-ray fluorescence and ptychography revealed a-so far unknown-lead-containing "layer", which likely acts as a protective impregnation layer applied on the canvas before the quartz-clay ground was applied. This layer might explain the presence of lead soap protrusions in areas where no other lead components are present. In addition to the three-dimensional elemental mapping, ptychography visualizes and quantifies components not detectable by hard x-ray fluorescence such as the organic fraction and quartz. The first-time use of this combination of synchrotron-based techniques on a historic paint micro-sample shows it to be an important tool to better interpret the results of noninvasive imaging techniques operating on the macroscale.
Language
English
Source (journal)
Science Advances
Publication
2023
ISSN
2375-2548
DOI
10.1126/SCIADV.ADJ9394
Volume/pages
9 :50 (2023) , p. 1-13
Article Reference
eadj9394
ISI
001142514700010
Pubmed ID
38100587
Medium
E-only publicatie
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Project info
Fusing microscopic and nanoscopic 3D data with macroscopic 2D mapping information for a better understanding of paint degradation phenomena in 17th. century masterpieces
CALIPSOplus: Convenient Access to Light Sources Open to Innovation, Science and to the World
Publication type
Subject
Art 
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 04.03.2024
Last edited 08.12.2024
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