Title
Electron impact mass spectrometric behaviour of bis(substituted benzoato) complexes of bis(<tex>$\eta$</tex>-cyclopentadienyl) titanium (IV)
Author
Faculty/Department
Faculty of Sciences. Chemistry
Faculty of Pharmaceutical, Biomedical and Veterinary Sciences. Pharmacy
Publication type
article
Publication
Subject
Chemistry
Source (journal)
Inorganica chimica acta
Volume/pages
201(1992) :2 , p. 185-190
ISSN
0020-1693
ISI
A1992JZ16900009
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The electron impact mass spectrometric behaviour of bis(cyclopentadienyl)-bis(benzoato)titanium(IV) and related phenyl substituted complexes containing a halogen atom (Cp2TiL2, with Cp = eta-C5H5; L = C6H5COO, (C6H5COO)-H-2, FC6H4COO or ClC6H4COO) is investigated with the aid of metastable ion analysis, deuterium labelling and determination of monoisotopic ion masses. Evidence is presented for the occurrence of intramolecular fluorine migrations, gas phase ion-molecule and ion-radical reactions and ortho effects.
E-info
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