Publication
Title
Electron impact mass spectrometric behaviour of bis(substituted benzoato) complexes of bis(-cyclopentadienyl) titanium (IV)
Author
Abstract
The electron impact mass spectrometric behaviour of bis(cyclopentadienyl)-bis(benzoato)titanium(IV) and related phenyl substituted complexes containing a halogen atom (Cp2TiL2, with Cp = eta-C5H5; L = C6H5COO, (C6H5COO)-H-2, FC6H4COO or ClC6H4COO) is investigated with the aid of metastable ion analysis, deuterium labelling and determination of monoisotopic ion masses. Evidence is presented for the occurrence of intramolecular fluorine migrations, gas phase ion-molecule and ion-radical reactions and ortho effects.
Language
English
Source (journal)
Inorganica chimica acta : f-block elements. - Lausanne, 1967, currens
Publication
Lausanne : 1992
ISSN
0020-1693 [print]
1873-3255 [online]
DOI
10.1016/S0020-1693(00)85330-X
Volume/pages
201 :2 (1992) , p. 185-190
ISI
A1992JZ16900009
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 08.10.2008
Last edited 13.12.2021
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