Title
Collision-induced spectra of hydrogen deuteride solution in liquid neon and their interpretation Collision-induced spectra of hydrogen deuteride solution in liquid neon and their interpretation
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
New York, N.Y. ,
Subject
Physics
Source (journal)
Physical review letters. - New York, N.Y.
Volume/pages
92(2004) :2 , 4 p.
ISSN
0031-9007
0031-9007
ISI
000188187100015
Carrier
E-only publicatie
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
First observation of the collision-induced IR-fundamental band of hydrogen deuteride (HD) in liquid neon is described. A developed intracell rattling model yields highly accurate fits to the measured diffuse Q(1)-branch profiles enabling a detailed shape analysis of the adjacent spectral lines. Strong intracollisional anticorrelation found at the location of the permanent dipole-allowed R-1(0) transition is interpreted in the frame of the Fano-Mori theory. A new striking narrowing effect (by 30%) is observed on the sharp Q(1)(q)(0) vibrational line with increasing HD concentration in solutions. The T-1(0), U-1(0) and a few pair transitions are identified in the spectrum.
Full text (open access)
https://repository.uantwerpen.be/docman/irua/d235e2/7804.pdf
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