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Title
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Collision-induced spectra of hydrogen deuteride solution in liquid neon and their interpretation
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Author
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Abstract
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| First observation of the collision-induced IR-fundamental band of hydrogen deuteride (HD) in liquid neon is described. A developed intracell rattling model yields highly accurate fits to the measured diffuse Q(1)-branch profiles enabling a detailed shape analysis of the adjacent spectral lines. Strong intracollisional anticorrelation found at the location of the permanent dipole-allowed R-1(0) transition is interpreted in the frame of the Fano-Mori theory. A new striking narrowing effect (by 30%) is observed on the sharp Q(1)(q)(0) vibrational line with increasing HD concentration in solutions. The T-1(0), U-1(0) and a few pair transitions are identified in the spectrum. |
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Language
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English
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Source (journal)
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Physical review letters. - New York, N.Y., 1958, currens
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Publication
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New York, N.Y.
:
American Physical Society
,
2004
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ISSN
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0031-9007
[print]
1079-7114
[online]
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DOI
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10.1103/PHYSREVLETT.92.023002
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Volume/pages
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92
:2
(2004)
, 4 p.
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Article Reference
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023002
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ISI
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000188187100015
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Medium
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E-only publicatie
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Full text (Publisher's DOI)
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Full text (open access)
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