Publication
Title
Collision-induced spectra of hydrogen deuteride solution in liquid neon and their interpretation
Author
Abstract
First observation of the collision-induced IR-fundamental band of hydrogen deuteride (HD) in liquid neon is described. A developed intracell rattling model yields highly accurate fits to the measured diffuse Q(1)-branch profiles enabling a detailed shape analysis of the adjacent spectral lines. Strong intracollisional anticorrelation found at the location of the permanent dipole-allowed R-1(0) transition is interpreted in the frame of the Fano-Mori theory. A new striking narrowing effect (by 30%) is observed on the sharp Q(1)(q)(0) vibrational line with increasing HD concentration in solutions. The T-1(0), U-1(0) and a few pair transitions are identified in the spectrum.
Language
English
Source (journal)
Physical review letters. - New York, N.Y.
Publication
New York, N.Y. : 2004
ISSN
0031-9007
Volume/pages
92:2(2004), 4 p.
Article Reference
023002
ISI
000188187100015
Medium
E-only publicatie
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 08.10.2008
Last edited 12.11.2017
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