Title
Displacive-replacive phase transformation in a <tex>$Ni_{62.5}Al_{37.5}$</tex> phase studies by HREM and microdiffraction Displacive-replacive phase transformation in a <tex>$Ni_{62.5}Al_{37.5}$</tex> phase studies by HREM and microdiffraction
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
London ,
Subject
Physics
Source (journal)
Philosophical magazine: B: physics of condensed matter: electronic, optical and magnetic properties. - London, 1978 - 2002
Volume/pages
67(1993) , p. 673-689
67(1993) :5 , p. 673-689
ISSN
1364-2812
0141-8637
0958-6644
0141-8637
ISI
A1993LF72000005
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The structure of the metastable Ni2Al phase, which has long been a matter of controversy, has been carefully re-examined by means of high-resolution transmission electron microscopy (HREM) and electron microdiffraction. First, it is concluded that theas-quenched NixAl100-x(60 less-than-or-equal-to x less-than-or-equal-to 65) material already exhibits a partial omega-type collapse in a one-dimensional fashion which and is consistent with the anomalous dip in the phonon dispersion curve. Ni2Al precipitates are formed on annealing by thermal decomposition of the high-temperature NixAl100-xB2 phase and still retain the small omega-type shuffle. The amount of displacement in the well developed Ni2Al phase was estimated to be between 20 and 50% of the ideal omega collapse; this was determined by means of a combined technique of HREM and microdiffraction together with dynamical calculations of HREM images and diffraction intensities.
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