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Publication
Title
Study of atmospheric MOCVD of thin films by means of computational fluid dynamics simulations
Author
Abstract
This paper presents the computational study of the metal-organic (MO) CVD of titanium dioxide (TiO2) films grown using titanium tetraisopropoxide (TTIP) as a precursor and nitrogen as a carrier gas. The TiO2 films are deposited under atmospheric pressure. The effects of the precursor concentration, the substrate temperature, and the hydrolysis reaction on the deposition process are investigated. It is found that hydrolysis of the TTIP decreases the onset temperature of the gas-phase thermal decomposition, and that the deposition rate increases with the precursor concentration and with the decrease of substrate temperature. Concerning the mechanism responsible for the film growth, the model shows that at the lowest precursor concentration, the direct adsorption of the precursor is dominant, while at higher precursor concentrations, the monomer deposition becomes more important.
Language
English
Source (journal)
Chemical vapor deposition. - Weinheim
Publication
Weinheim : 2008
ISSN
0948-1907 [print]
1521-3862 [online]
DOI
10.1002/CVDE.200806708
Volume/pages
14 :11/12 (2008) , p. 339-346
ISI
000262215800003
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier c:irua:71905
Creation 07.01.2009
Last edited 13.11.2024
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