Title
Synthesis of (alkylamino)nitroarenes by oxidative alkylamination of nitroarenesSynthesis of (alkylamino)nitroarenes by oxidative alkylamination of nitroarenes
Author
Faculty/Department
Faculty of Sciences. Chemistry
Research group
Organic synthesis
Molecular Spectroscopy
Publication type
article
Publication
Weinheim,
Subject
Chemistry
Source (journal)
European journal of organic chemistry. - Weinheim
Volume/pages
(2009):4, p. 564-574
ISSN
1434-193X
ISI
000263086600011
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The viability of the oxidative alkylamination process for the derivatization of electron-deficient carboaromatics has been investigated. 1,3-Dinitrobenzene, 1-nitronaphthalene, and 1,5- and 1,8-dinitronaphthalenes have shown to react with a wide range of alkylamines in the presence of an oxidant (KMnO4, AgMnO4, AgPy2MnO4) to give access to the corresponding N-alkyl-nitroarenamines in moderate to good yields. Nitroarenes are more reactive than azines towards alkylamines.
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