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Title
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Synthesis of (alkylamino)nitroarenes by oxidative alkylamination of nitroarenes
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Author
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Abstract
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| The viability of the oxidative alkylamination process for the derivatization of electron-deficient carboaromatics has been investigated. 1,3-Dinitrobenzene, 1-nitronaphthalene, and 1,5- and 1,8-dinitronaphthalenes have shown to react with a wide range of alkylamines in the presence of an oxidant (KMnO4, AgMnO4, AgPy2MnO4) to give access to the corresponding N-alkyl-nitroarenamines in moderate to good yields. Nitroarenes are more reactive than azines towards alkylamines. |
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Language
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English
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Source (journal)
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European journal of organic chemistry. - Weinheim, 1998, currens
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Publication
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Weinheim
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2009
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ISSN
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1434-193X
[print]
1099-0690
[online]
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DOI
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10.1002/EJOC.200800740
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Volume/pages
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4
(2009)
, p. 564-574
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ISI
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000263086600011
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Full text (Publisher's DOI)
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