Title
Synthesis of 5-methyl-5**H**-pyrrolo[2,3-**c**]quinoline and 4-methyl-4**H**-pyrrolo[2,3-c]isoquinoline: two new unnatural D-ring stripped isomers of the cryptolepine series Synthesis of 5-methyl-5**H**-pyrrolo[2,3-**c**]quinoline and 4-methyl-4**H**-pyrrolo[2,3-c]isoquinoline: two new unnatural D-ring stripped isomers of the cryptolepine series
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
,
Subject
Chemistry
Source (journal)
Arkivoc : online journal of organic chemistry. - Place of publication unknown, 2000, currens
Volume/pages
(2009) :6 , p. 174-182
ISSN
1551-7004
1424-6369
ISI
000266695800018
Carrier
E
Target language
English (eng)
Affiliation
University of Antwerp
Abstract
5-Methyl-5H-pyrrolo[2,3-c]quinoline and 4-methyl-4H-pyrrolo[2,3-c]isoquinoline have been synthesized via a domino condensation Heck cyclisation of, espectively, 4-bromoquinolin-3-amine or 4-bromoisoquinolin-3-amine and acetaldehyde. Selective methylation of the tricyclic skeletons yielded the title compounds 5-methyl-5H-pyrrolo[2,3-c]quinoline and 4-methyl-4Hpyrrolo[2,3-c]isoquinoline.
Full text (open access)
https://repository.uantwerpen.be/docman/irua/aa77bb/d31c1403.pdf
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