Publication
Title
Synthesis and crystal structure of new titanyl phosphate
Author
Abstract
New strontium titanyl phosphate Sr2TiO(PO4)2 (1) was synthesized and characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and band structure calculations. Titanyl phosphate 1 is isostructural with vanadyl phosphate Sr2VO(PO4)2 and has a layered structure. The titanium atoms are shifted from the centers of the TiO6 octahedra and form short (1.74 Å) titanyl bonds. The structure of 1 is an unusual example of the disordered orientation of the chains formed by TiO6 octahedra in complex titanium phosphates.
Language
English
Source (journal)
Russian chemical bulletin
Publication
2008
ISSN
1066-5285
DOI
10.1007/S11172-008-0085-9
Volume/pages
57 :3 (2008) , p. 552-556
ISI
000263566900015
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 13.03.2009
Last edited 28.08.2024
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