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Title
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Synthesis and crystal structure of new titanyl phosphate
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Author
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Abstract
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| New strontium titanyl phosphate Sr2TiO(PO4)2 (1) was synthesized and characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and band structure calculations. Titanyl phosphate 1 is isostructural with vanadyl phosphate Sr2VO(PO4)2 and has a layered structure. The titanium atoms are shifted from the centers of the TiO6 octahedra and form short (1.74 Å) titanyl bonds. The structure of 1 is an unusual example of the disordered orientation of the chains formed by TiO6 octahedra in complex titanium phosphates. |
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Language
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English
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Source (journal)
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Russian chemical bulletin
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Publication
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2008
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ISSN
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1066-5285
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DOI
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10.1007/S11172-008-0085-9
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Volume/pages
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57
:3
(2008)
, p. 552-556
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ISI
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000263566900015
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Full text (Publisher's DOI)
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