Title
Inequivalent electron densities derived from an approximate correlated ground-state wave function using the Hiller-Sucher-Feinberg identity: comparisons with quantum Monte Carlo densities for He and Ne atoms Inequivalent electron densities derived from an approximate correlated ground-state wave function using the Hiller-Sucher-Feinberg identity: comparisons with quantum Monte Carlo densities for He and Ne atoms
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
New York, N.Y. ,
Subject
Physics
Source (journal)
International journal of quantum chemistry. - New York, N.Y.
Volume/pages
109(2009) :5 , p. 1024-1030
ISSN
0020-7608
ISI
000263710800012
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The Hiller-Sucher-Feinberg (HSF) identity is combined with the three-parameter correlated wave function of Chandrasekhar in order to generate an alternative electron density (r) for the He atom. This and the conventional local operator form of (r) are then compared with a diffusion quantum Monte Carlo density. An exact limiting relation is also presented, via HSF identity, between the one-particle density matrix and the pair density in a many-electron atom, which transcends its Hartree-Fock counterpart and has no N-representability difficulties. For the Ne atom, the accuracy of the semiempirical correlated electron density recently obtained by Cordero et al. (Phys. Rev. A 2007, 75, 052502) using fine-tuning of Hartree-Fock theory was assessed by appealing to the ground-state density from diffusion quantum Monte Carlo. The high accuracy of the Cordero et al. density was thereby confirmed. A HSF calculation on neon, with a correlated many-body wave function as starting point, is a worthwhile future aim.
E-info
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000263710800012&DestLinkType=RelatedRecords&DestApp=ALL_WOS&UsrCustomerID=ef845e08c439e550330acc77c7d2d848
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000263710800012&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=ef845e08c439e550330acc77c7d2d848
Handle