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Title
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Self-doping PPV oligomers: electrochemistry and structure of the self-doped systems
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Author
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Abstract
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| A novel class of self-doping conjugated oligomers, E,E-2-(sulfoalkoxy)-5-alkoxy-1,4-bis[2-(2,4,6-trimethoxyphenyl) ethenyl]benzenes, is presented. The synthesis and spectroscopic characterisation of five such oligomers are described, and an electrochemical analysis using cyclic voltammetry is performed to determine the anodic peak potentials. A structural study is performed on six self-doping oligomers in which the structures and energies of the possible mono-molecular forms of the electrically conducting doped material are described and evaluated using Hirshfeld charges and the Quantum Theory of Atoms In Molecules |
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Language
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English
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Source (journal)
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Journal of physical organic chemistry. - Chichester
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Publication
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Chichester
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2009
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ISSN
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0894-3230
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DOI
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10.1002/POC.1542
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Volume/pages
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22
:10
(2009)
, p. 925-932
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ISI
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000270421800004
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Full text (Publisher's DOI)
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