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Title
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Molecular and crystal structures of (M = Co, Rh, Ir) and related compounds
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Author
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Abstract
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| Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low-temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. |
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Language
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English
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Source (journal)
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European journal of inorganic chemistry. - Weinheim, 1998, currens
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Publication
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Weinheim
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2009
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ISSN
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1434-1948
[print]
1099-0682
[online]
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Volume/pages
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29/30
(2009)
, p. 4483-4490
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ISI
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000271572100015
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Full text (Publisher's DOI)
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