Publication
Title
On the $\nu_{1}^{CO_{2}}/2\nu_{2}^{CO_{2}}$ resonance in the complex of carbon dioxide with dimethyl ether
Author
Abstract
 Infrared and Raman spectra of solutions in liquid argon and krypton containing dimethyl ether or its fully deuterated isotopomer and 12CO2 or 13CO2 are investigated. The spectra lead to new data on the 1CO2/2 2CO2 resonances appearing in the complex of CO2 with the ether. The experimental data, and their interpretation, is supported by MP2/6-311++G(2d,2p) calculations of the cubic and quartic force constants and of the first and higher order dipole moment derivatives required for the modelling of the Fermi and Darling-Dennison resonances observed.
Language
English
Source (journal)
ChemPhysChem: a European journal of chemical physics and physical chemistry. - Weinheim
Publication
Weinheim : 2009
ISSN
1439-4235
Volume/pages
10:17(2009), p. 3054-3060
ISI
000272786900015
Full text (Publishers DOI)
Full text (publishers version - intranet only)
UAntwerpen
 Faculty/Department Research group Publication type Subject Affiliation Publications with a UAntwerp address