Publication
Title
Synthesis and structures of substituted triphenyl(phenylimino)phosphoranes
Author
Abstract
Three substituted triphenyl(phenylimino)phosphoranes, namely (4-cyanophenylimino)triphenylphosphorane, C25H19N2P, (I), (4-nitrophenylimino)triphenylphosphorane, C24H19N2O2P, (II), and (3-nitrophenylimino)triphenylphosphorane, C24H19N2O2P, (III), were synthesized as precursors for the preparation of substituted diphenylcarbodiimides. All three compounds display a supramolecular arrangement in which the substituted benzene rings are organized in an antiparallel fashion. The nitro group on the ring participates in CH...O and O...π interactions, forming intermolecular dimers. Compound (III) shows disorder which involves the rotation of one of the phenyl rings of the triphenylphosphine group.
Language
English
Source (journal)
Acta crystallographica: section C: crystal structure communications. - Copenhagen
Publication
Copenhagen : 2010
ISSN
0108-2701
Volume/pages
66:1(2010), p. o50-o54
ISI
000273265100019
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 18.02.2010
Last edited 17.10.2017
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