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Title
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Characterization and quantification of isoprene-derived epoxydiols in ambient aerosol in the southeastern United State
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Author
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Abstract
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| Isoprene-derived epoxydiols (IEPOX) are identified in ambient aerosol samples for the first time, together with other previously identified isoprene tracers (i.e., 2-methyltetrols, 2-methylglyceric acid, C5-alkenetriols, and organosulfate derivatives of 2-methyltetrols). Fine ambient aerosol collected in downtown Atlanta, GA and rural Yorkville, GA during the 2008 August Mini-Intensive Gas and Aerosol Study (AMIGAS) was analyzed using both gas chromatography/quadrupole mass spectrometry (GC/MS) and gas chromatography/time-of-flight mass spectrometry (GC/TOFMS) with prior trimethylsilylation. Mass concentrations of IEPOX ranged from 1 to 24 ng m−3 in the aerosol collected from the two sites. Detection of particle-phase IEPOX in the AMIGAS samples supports recent laboratory results that gas-phase IEPOX produced from the photooxidation of isoprene under low-NOx conditions is a key precursor of ambient isoprene secondary organic aerosol (SOA) formation. On average, the sum of the mass concentrations of IEPOX and the measured isoprene SOA tracers accounted for about 3% of the organic carbon, demonstrating the significance of isoprene oxidation to the formation of ambient aerosol in this region. |
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Language
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English
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Source (journal)
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Environmental science and technology / American Chemical Society. - Easton, Pa
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Publication
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Easton, Pa
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2010
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ISSN
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0013-936X
[print]
1520-5851
[online]
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DOI
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10.1021/ES100596B
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Volume/pages
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44
:12
(2010)
, p. 4590-4596
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ISI
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000278617000036
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Full text (Publisher's DOI)
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