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Title
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Cation ordering within the perovskite block of a six-layer Ruddlesden-Popper oxide from layer-by-layer growth artificial interfaces in complex unit cells
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Author
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Abstract
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| The (AO)(ABO3)n Ruddlesden-Popper structure is an archetypal complex oxide consisting of two distinct structural units, an (AO) rock salt layer separating an n-octahedra thick perovskite block. Conventional high-temperature oxide synthesis methods cannot access members with n > 3, but low-temperature layer-by-layer thin film methods allow the preparation of materials with thicker perovskite blocks, exploiting high surface mobility and lattice matching with the substrate. This paper describes the growth of an n = 6 member CaO[(CSMO)2(LCMO)2 (CSMO)2] in which the six unit cell perovskite block is sub-divided into two central La0.67Ca0.33MnO3 (LCMO) and two terminal Ca0.85Sm0.15MnO3 (CSMO) layers to allow stabilization of the rock salt layer and variation of the transition metal charge. |
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Language
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English
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Source (journal)
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Chemical science. - Cambridge, 2010, currens
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Publication
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Cambridge
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Royal Society of Chemistry
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2011
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ISSN
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2041-6520
[print]
2041-6539
[online]
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DOI
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10.1039/C0SC00482K
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Volume/pages
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2
:2
(2011)
, p. 261-272
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ISI
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000286327600010
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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