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Title
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Monolayer graphene from graphite oxide
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Author
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Abstract
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| Graphene, a new carbon material, is attracting presently an increasing research interest. It stems from the unique electrical and mechanical properties of graphene predicted by theory. Experimental studies of graphene are, however, severely curtailed by a lack of an appropriate technique for its preparation. Mechanical cleavage of graphite proved to be ineffective, since it yields only very small (a few microns in size) particles of monolayer graphene. The rapidly developing approach based on chemical exfoliation of graphite produces large-area coatings composed primarily of arbitrarily oriented multilayer graphene particles. We have developed a technique for preparation of monolayer graphene sheets involving liquid exfoliation of crystalline graphite, which includes synthesis of graphite oxide by deep oxidation as an intermediate stage. Electron diffraction traces, as well as the variation of diffracted intensities with local orientation of graphene sheets, AFM, and HRTEM images testify to a remarkably good monolayer structure of the graphite oxide particles obtained by our technique. These results open a way to setting up high-efficiency production of monolayer graphene sheets appropriate for electrical and optical measurements and fabrication of structures for use in the field of applications. |
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Language
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English
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Source (journal)
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Diamond and related materials. - Amsterdam
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Publication
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Amsterdam
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2011
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ISSN
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0925-9635
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DOI
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10.1016/J.DIAMOND.2010.10.007
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Volume/pages
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20
:2
(2011)
, p. 105-108
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ISI
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000288145500010
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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