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Title
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Extension of the clathrate family : the type X clathrate
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Author
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Abstract
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| Now they are 10! The title compound displays a new type of crystal structure and is labeled clathrate X according to the general classification of clathrate structures. In contrast to typical clathrates, this compound has three-coordinate atoms within the framework and combines distorted 24-vertex polyhedra (see picture, green) centered around tellurium guest atoms with very irregular 10-vertex polyhedra around sulfur atoms (yellow). |
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Language
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English
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Source (journal)
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Angewandte Chemie: international edition in English. - Weinheim
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Publication
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Weinheim
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2011
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ISSN
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1433-7851
0570-0833
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DOI
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10.1002/ANIE.201007483
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Volume/pages
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50
:10
(2011)
, p. 2371-2374
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ISI
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000288036300033
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Full text (Publisher's DOI)
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