Title
Electrochemical deposition of dodecanoate on lead in view of an environmentally safe corrosion inhibitionElectrochemical deposition of dodecanoate on lead in view of an environmentally safe corrosion inhibition
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Subject
Physics
Chemistry
Source (journal)
Journal of solid state electrochemistry
Volume/pages
14(2010):3, p. 407-413
ISSN
1432-8488
ISI
000273175600008
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Abstract
Non-toxic linear sodium monocarboxylates can be successfully used as inhibitors for the corrosion of many metals. The adsorption of these molecules onto a metal is usually achieved by immersing the metal in the carboxylate solution for a few hours. This paper describes the strength of cyclic voltammetry in forming a sodium dodecanoate coating on a lead electrode. We show that this approach is much less time-consuming compared with the immersion method and enables one to control and to characterize the layer formed by following the potential and current during the process. Additional ATR-IR and X-ray diffraction spectroscopic analyses were performed to qualitatively characterize the newly formed coating.
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