Title Dimerization constant of $SF_{6}$ and $CF_{4}$ in cryosolutions Author Dobrotvorskaia, A.N. Shchepkin, D.N. Sergeev, P.K. Herrebout, W.A. van der Veken, B.J. Faculty/Department Faculty of Sciences. Chemistry Publication type article Publication 2011 Amsterdam , 2011 Subject Physics Chemistry Source (journal) Chemical physics. - Amsterdam Volume/pages 382(2011) :1/3 , p. 27-33 ISSN 0301-0104 ISI 000291255100005 Carrier E Target language English (eng) Full text (Publishers DOI) Affiliation University of Antwerp Abstract Infrared absorption spectra of SF6 and CF4 solutions in liquid O2, N2 and Ar were studied in the temperature interval T = 64110 K. With the use of these spectra the monomer-dimer equilibrium constant has been examined to realize the process of the dimer formation. The equilibrium constant is established to be rather constant with the temperature and cryosolvents, whence it was concluded that the dimer formation process is entirely probabilistic phenomenon in low-temperature solutions. E-info http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000291255100005&DestLinkType=RelatedRecords&DestApp=ALL_WOS&UsrCustomerID=ef845e08c439e550330acc77c7d2d848 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000291255100005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=ef845e08c439e550330acc77c7d2d848 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000291255100005&DestLinkType=CitingArticles&DestApp=ALL_WOS&UsrCustomerID=ef845e08c439e550330acc77c7d2d848 Handle