Title
Dimerization constant of <tex>$SF_{6}$</tex> and <tex>$CF_{4}$</tex> in cryosolutions Dimerization constant of <tex>$SF_{6}$</tex> and <tex>$CF_{4}$</tex> in cryosolutions
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Amsterdam ,
Subject
Physics
Chemistry
Source (journal)
Chemical physics. - Amsterdam
Volume/pages
382(2011) :1/3 , p. 27-33
ISSN
0301-0104
ISI
000291255100005
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Infrared absorption spectra of SF6 and CF4 solutions in liquid O2, N2 and Ar were studied in the temperature interval T = 64110 K. With the use of these spectra the monomer-dimer equilibrium constant has been examined to realize the process of the dimer formation. The equilibrium constant is established to be rather constant with the temperature and cryosolvents, whence it was concluded that the dimer formation process is entirely probabilistic phenomenon in low-temperature solutions.
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