Publication
Title
Elucidating the nature and reactivity of Ti ions incorporated in the framework of AlPO-5 molecular sieves : new evidence from HYSCORE spectroscopy
Author
Abstract
The incorporation of Ti ions within the framework of aluminophosphate zeotype AlPO-5 and their chemical reactivity is studied by means of CW-EPR, HYSCORE, and UVvis spectroscopies. Upon reduction, Ti3+ ions are formed, which exhibit large 31P hyperfine couplings, providing direct evidence for framework substitution of reducible Ti ions at Al sites.
Language
English
Source (journal)
Journal of the American Chemical Society. - Washington, D.C., 1879, currens
Journal of the American Chemical Society. - Washington, D.C., 1879, currens
Publication
Washington, D.C. : American Chemical Society , 2011
ISSN
0002-7863
Volume/pages
133 :19 (2011) , p. 7340-7343
ISI
000290782200027
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 15.07.2011
Last edited 30.11.2021
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