Title
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Surface atomic structure of KDP crystals in aqueous solution ; an explanation of the growth shape
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Author
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Abstract
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With this study on KDP, we present an interface atomic structure determination of a crystal in contact with its growth solution. Using x-ray diffraction at a third-generation synchrotron radiation source, the structure of both the {101} and {100} faces has been determined. We found that the {101} faces are terminated by a layer of K+ ions and not by H2PO4- groups, resolving a long-standing issue that could not be predicted by theory. This result leads to an atomic-scale explanation of the influence of metal impurities on the macroscopic growth morphology. |
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Language
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English
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Source (journal)
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Physical review letters. - New York, N.Y., 1958, currens
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Publication
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New York, N.Y.
:
American Physical Society
,
1998
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ISSN
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0031-9007
[print]
1079-7114
[online]
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DOI
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10.1103/PHYSREVLETT.80.2229
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Volume/pages
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80
:10
(1998)
, p. 2229-2232
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ISI
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000072385400051
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Full text (Publisher's DOI)
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Full text (open access)
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