Publication
Title
Hydrogen-bond patterns in solid-state carboxylic-acids - vibrational study of the hydrogen-bond patterns in oxamic, malonamic and succinamic acid
Author
Abstract
The vibrational spectra of oxamic, malonamic and succinamic acid are reported, Although these molecules exhibit identical functional groups, their solid state hydrogen bond patterns can be divided in two different types, which can be clearly distinguished through the combination of infrared and Raman spectroscopy at variable temperatures and through the vibrational behaviour of the deuterated compounds, Oxamic acid behaves as a linear hydrogen bonded polymer with cyclic acid-acid and cyclic amide-amide dimers while the other discussed carboxylic acid derivatives exhibit a cyclic acid-amide hydrogen bond pattern, A model is proposed to investigate the peculiar vibrational behaviour of oxamic ai:id theoretically. Spectroscopic studies of the cyclic heterogenic acid-amide hydrogen bond pattern are studied for the first time.
Language
English
Source (journal)
Spectrochimica acta: part A: molecular and biomolecular spectroscopy. - Oxford
Publication
Oxford : 1995
ISSN
1386-1425
Volume/pages
51:10, p. 1601-1615
ISI
A1995TD75700002
Full text (Publisher's DOI)
UAntwerpen
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 29.02.2012
Last edited 06.07.2017