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Title
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Temperature dependence of the liquid structure factor of dense monatomic fluids in the long wavelength limit in relation to thermal expansivity
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Author
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Abstract
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| The temperature dependence of the liquid structure factor S(k) of dense monatomic fluids, and especially a variety of liquid metals, is studied by combining thermodynamics and fluctuation theory in the long wavelength limit k -> 0. Emphasis is placed on the connection of partial derivative S(0)/partial derivative T with thermal expansivity. Reference here is then made to recent semiempirical work of Lawson, who advocated an approximate relation, but at the melting temperature T-m, between [S(0)](Tm) and the Gruneisen constant. |
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Language
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English
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Source (journal)
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Philosophical magazine letters. - London
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Publication
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London
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2012
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ISSN
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0950-0839
[print]
1362-3036
[online]
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DOI
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10.1080/09500839.2011.640643
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Volume/pages
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92
:3
(2012)
, p. 133-135
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ISI
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000300398400004
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Full text (Publisher's DOI)
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