Title
On the behavior of nitrogen-oxides in liquefied argon and krypton : dimerization of nitric-oxide On the behavior of nitrogen-oxides in liquefied argon and krypton : dimerization of nitric-oxide
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Amsterdam ,
Subject
Chemistry
Source (journal)
Journal of molecular structure. - Amsterdam
Volume/pages
320(1994) , p. 249-267
ISSN
0022-2860
ISI
A1994NH31400022
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Solutions containing several nitrogen oxide species have been investigated in liquefied argon in the temperature range 84-105 K, and in liquefied krypton in the temperature range 116-150 K, using infrared spectroscopy. The following nitrogen oxide species were characterised in these solutions: NO, cis-ONNO, trans-ONNO, the asymmetric dimer ONON, asymmetric ONNO2, Symmetric ONONO and N2O4 with D2h symmetry. The enthalpy of dimerisation of NO to cis-ONNO has been determined in liquefied argon to be -14.3 +/- 1 kJ mol-1.
E-info
https://repository.uantwerpen.be/docman/iruaauth/a0d6c5/a954386.pdf
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