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On the behavior of nitrogen-oxides in liquefied argon and krypton : dimerization of nitric-oxide
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| Abstract |
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| Solutions containing several nitrogen oxide species have been investigated in liquefied argon in the temperature range 84-105 K, and in liquefied krypton in the temperature range 116-150 K, using infrared spectroscopy. The following nitrogen oxide species were characterised in these solutions: NO, cis-ONNO, trans-ONNO, the asymmetric dimer ONON, asymmetric ONNO2, Symmetric ONONO and N2O4 with D2h symmetry. The enthalpy of dimerisation of NO to cis-ONNO has been determined in liquefied argon to be -14.3 +/- 1 kJ mol-1. |
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| Language |
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English
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| Source (journal) |
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Journal of molecular structure. - Amsterdam |
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Amsterdam : 1994
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0022-2860
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320(1994), p. 249-267
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| ISI |
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A1994NH31400022
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| Full text (publisher's version - intranet only) |
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