Publication
Title
The vibrational spectra of complexes with planar monothiooxamides : IV. the copper(II) and copper(I) complexes of neutral monothiooxamides
Author
Abstract
The new complexes CuX(2)(LH(2)), CuX(2) (SH3) (X = Cl, Br), CuX(LH(2)), CuX(SH3) (X = Cl, Br, l), CuX(H(4)MTO)2 (X = Cl, Br), CUI(H(4)MTO) and CuX(H(3)MMTO)2 (X = Cl, Br, l), where LH(2) = N,N'-dimethylmonothiooxamide, SH3 = N-(s)-methylmonothiooxamide, H(4)MTO = monothiooxamide and H(3)MMTO = N-(o)-methylmonothiooxamide, have been prepared. The complexes were characterized by elemental analyses, conductivity measurements,magnetic moments and spectroscopic (UV/VIS, FT-IR, Laser-Raman) studies. The vibrational analysis of the complexes has been given using NH/ND, CH3/CD3 and (CU)-C-63/(CU)-C-65 isotopic substitutions. The neutral monothiooxamides behave as monodentate ligands in the Cu(l) complexes coordinating through their thioamide sulfur atom. The ligands LH(2) and SH3 act as bidentate chelating agents in the Cu(ll) complexes with ligated atoms being the thioamide sulfur and the amide oxygen.
Language
English
Source (journal)
Spectroscopy letters. - New York
Publication
New York : 1994
ISSN
0038-7010
Volume/pages
27:1(1994), p. 119-138
ISI
A1994MT29700009
Full text (Publishers DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 19.07.2012
Last edited 09.04.2017
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