Title
The vibrational spectra of complexes with planar monothiooxamides : IV. the copper(II) and copper(I) complexes of neutral monothiooxamides The vibrational spectra of complexes with planar monothiooxamides : IV. the copper(II) and copper(I) complexes of neutral monothiooxamides
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
New York ,
Subject
Chemistry
Source (journal)
Spectroscopy letters. - New York
Volume/pages
27(1994) :1 , p. 119-138
ISSN
0038-7010
ISI
A1994MT29700009
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The new complexes CuX(2)(LH(2)), CuX(2) (SH3) (X = Cl, Br), CuX(LH(2)), CuX(SH3) (X = Cl, Br, l), CuX(H(4)MTO)2 (X = Cl, Br), CUI(H(4)MTO) and CuX(H(3)MMTO)2 (X = Cl, Br, l), where LH(2) = N,N'-dimethylmonothiooxamide, SH3 = N-(s)-methylmonothiooxamide, H(4)MTO = monothiooxamide and H(3)MMTO = N-(o)-methylmonothiooxamide, have been prepared. The complexes were characterized by elemental analyses, conductivity measurements,magnetic moments and spectroscopic (UV/VIS, FT-IR, Laser-Raman) studies. The vibrational analysis of the complexes has been given using NH/ND, CH3/CD3 and (CU)-C-63/(CU)-C-65 isotopic substitutions. The neutral monothiooxamides behave as monodentate ligands in the Cu(l) complexes coordinating through their thioamide sulfur atom. The ligands LH(2) and SH3 act as bidentate chelating agents in the Cu(ll) complexes with ligated atoms being the thioamide sulfur and the amide oxygen.
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