Publication
Title
The vibrational-spectra of complexes with planar monothiooxamides .3. the palladium(ii) complexes of neutral monothiooxamides
Author
Abstract
The new complexes trans-[PdX(2)(H(4)MTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(H(3)MMTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(SH3)(2)] (X= Cl, Br, l), [Pd(H(4)MTO)(4)]Cl-2 and [Pd(H(3)MMTO)(4)]Cl-2, where H(4)MTO= monothiooxamide, H(3)MMTO = N(o)-methylmonothiooxamide and SH3 = N(s)-methylmonothiooxamide, have been prepared. The complexes were characterized by elemental analyses, conductivity measurements, X-ray powder patterns, thermal methods and spectroscopic (UV/VIS, FT-IR, Laser-Raman) studies. The vibrational analysis of the complexes is given using NH/ND and CH3/CD3 isotopic substitutions. Monomeric square planar structures are assigned for the complexes in the solid state. The neutral monothiooxamides behave as monodentate ligands coordinating through their thioamide sulfur atom. The complex [Pd(SH2)(2)] was isolated during the thermal decomposition of trans - [PdCl2(SH3)(2)].
Language
English
Source (journal)
Spectroscopy letters. - New York
Publication
New York : 1994
ISSN
0038-7010
Volume/pages
27:1(1994), p. 97-118
ISI
A1994MT29700008
Full text (Publishers DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 19.07.2012
Last edited 26.05.2017
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