Title
The vibrational-spectra of complexes with planar monothiooxamides .3. the palladium(ii) complexes of neutral monothiooxamides The vibrational-spectra of complexes with planar monothiooxamides .3. the palladium(ii) complexes of neutral monothiooxamides
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
New York ,
Subject
Chemistry
Source (journal)
Spectroscopy letters. - New York
Volume/pages
27(1994) :1 , p. 97-118
ISSN
0038-7010
ISI
A1994MT29700008
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The new complexes trans-[PdX(2)(H(4)MTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(H(3)MMTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(SH3)(2)] (X= Cl, Br, l), [Pd(H(4)MTO)(4)]Cl-2 and [Pd(H(3)MMTO)(4)]Cl-2, where H(4)MTO= monothiooxamide, H(3)MMTO = N(o)-methylmonothiooxamide and SH3 = N(s)-methylmonothiooxamide, have been prepared. The complexes were characterized by elemental analyses, conductivity measurements, X-ray powder patterns, thermal methods and spectroscopic (UV/VIS, FT-IR, Laser-Raman) studies. The vibrational analysis of the complexes is given using NH/ND and CH3/CD3 isotopic substitutions. Monomeric square planar structures are assigned for the complexes in the solid state. The neutral monothiooxamides behave as monodentate ligands coordinating through their thioamide sulfur atom. The complex [Pd(SH2)(2)] was isolated during the thermal decomposition of trans - [PdCl2(SH3)(2)].
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